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Frankfurt’s neighborhoods each have distinct character and charm. Sachsenhausen, with its cobblestone streets and museums, is for those who like to experience a city’s historic and cultural heritage. Ostend and Nordend, with their many cafes and boutiques, are perfect for a daytime walk, while Westend — the old bourgeois district —is where the beautiful botanical garden, Palmergarten,is located.

On your next trip to Europe, don't just pass through Frankfurt's airport. Instead, take time todiscover Germany’s fifth largest city.

What to Do in Frankfurt

Frankfurt has a number of exciting seasonal events worth noting on your calendar, such as Oktoberfest (in September), the annual Christmas market (in December), and the Frankfurt Book Fair (in October), among others . There is something interesting happening in Frankfurt at any given time of the year.

Of course, there are permanent attractions to keep you entertained, too. Art aficionados should head to Sachsenhausen, the neighborhood south of the river, where the city’s so-called Museum Mileis located. It’s home to the German Film Museum, the Communication Museum, and Staedel Museum, among many others. If you’re planning on visiting more than one, purchase the MuseumSufer ticket , which includes access to 34 museums for two consecutive days.

This 200-year-old institution houses one of the world’s most impressive and important collections, documenting 700 years of art history alongside Washington Suede Tassel Loafers Discount Popular PVAxiN
. Visitors may recognize popular works of art such as Edgar Degas’ “Orchestra Musicians,” Claude Monet’s “The Luncheon,” and Rembrandt’s “The Blinding of Samson.” Other artists you’ll find in the museum ’s permanent collection include Vincent Van Gogh, Edvard Munch, and Picasso.

Courtesy of DialogMuseum

This museum redefines the common perception of a museum which, by definition, is a place where you go to see artifacts:see being the key word. The concept behind Sale Very Cheap JFWGASTON COMBO Trainers cognac Cheap Discount Sale Limited Edition Outlet Shop For Order Sale Online vnKlO
, on the other hand, is unusual but impactful. Guests join a one-hour guided tour that moves throughfour rooms where, in absolute darkness, you will get to experience daily life without any visual components, the way blind or visually impaired people do. (All guides, as a matter of fact, will be visually impaired.)You will be surprised at the range of emotions you can feel in just 60 minutes — utter hopelessness being a major one — but it’s an incredible experience. Make sure to reserve your tour spot in advance.

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Outline

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, 12 March 1991, Pages 217-227
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Oskar Nuyken Thomas Pöhlmann
https://doi.org/10.1016/0022-328X(91)86275-U Get rights and content

Ferrocenethiol and ferrocene-1,-1′-dithiol, Fe(CH)(CHSH) and Fe(CHSH) respectively, can be added to both norbornadiene and norbornene in a radical-induced process. The reaction of ferrocenethiol with norbornadiene (1 : 10) in toluene at 70°C gives a mixture of 1 : 1 addition products containing 3-ferrocenylthio-nortricyclane (I) as the main component (ca. 80%)l side-products are the substituted norbornene derivatives 5-- and 5--ferrocenylthio-norborn-2-ene (II and III) as well as 7--ferrocenylthio-norborn-2-ene (IV). Only traces of addition compounds containing ferrocenethiol and norbornadiene in a 2 : 1 ratio were obtained and identified by mass spectrometry.

The radical-initiated addition of ferrocenethiol to norbornene leads, even with an excess of norbornene, to the preferential formation of differocenyldisulfide in addition to 2-- and 2--ferrocenylthio-norbornane (V and VI). In an analogous manner, di[1′-(2--norbornylthio)ferrocenyl]disulfide (VII) is obtained from the reaction of ferrocene-1,1′-dithiol with excess norbornene. The new ferrocene-sulphur compounds I–VII were characterized by their H and C NMR spectra.

Ferrocenthiol und Ferrocen-1,1′-dithiol, Fe(CH)(CHSH)bzw. Fe(CHSH), lassen sich radikalisch an Norbornadien und Norbornen addieren. Die Umsetzung von Ferrocenthiol mit Norbornadien (1 : 10) in Toluol bei 70°C ergibt ein Gemisch von 1 : 1-Additionsprodukten, in dem 3-Ferrocenylthionortricyclan (I) dominiert (ca. 80%); Nebenprodukte sind die substituierten Norbornen-Derivate 5-- und 5--Ferrocenylthio-norborn-2-en (II und III) sowie 7--Ferrocenylthio-norborn-2-en (IV). 2 : 1-Additionsverbindungen von Ferrocenthiol und Norbornadien wurden nur in Spuren erhalten und massenspektrometrisch identifiziert.

Die radikalisch initiierte Anlagerung von Ferrocenthiol an Norbornen fürht auch bei Norbornen-Überschuß, bevorzugt zur Bildung von Diferrocenyldisulfid neben 2-- und 2--Ferrocenylthio-norbornan (V und VI). Bei der Reaktion von Ferrocen-1,1′-dithiol mit überschüssigem Norbornen wird entsprechend Di[1′-(2--norbornylthio)ferrocenyl]disulfid (VII) erhalten. Die neuen Ferrocen-Schwefel-Verbindungen I–VII wurden anhand ihrer H und C NMR-Spektren charakterisiert.

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